Hazard symbols and hazard pictograms chemical classification. Grantee materials by topic occupational safety and health. Signal code hazard statements hazard class category. The deadline for substance classification according to the new rules was 1 december 2010. Whmis pictograms, hazard classes, and hazard categories. However, the signal word, precautionary statements, and pictogram s must be located together on the label. Laboratory data guides the global harmonized system ghs codes and pictograms h200 physical hazards h200 unstable explosive h201 explosive.
The pictograms on the right are part of the new globally harmonized system ghs of classification and labeling. A hazard pictogram is an image on a label that includes a warning symbol and specific colours intended to provide information about the damage a particular substance or mixture can cause to our health or the environment. The diamondshaped pictograms indicate the nature of the hazard s associated with the use of a hazardous substance or mixture. Pictograms are standardized symbols that alert workers to the various hazards. The pictograms help us to know that the chemicals we are using might cause harm to people or the environment. Hazard pictograms according to clp regulation msds europe. Pesticides, biocides, petrol, turpentine, diesel examples of precautionary statements. The most noticeable feature is the change in the labeling symbols. As a first step, in addition to the industry perspective, insights were obtained from qualitative consumer research and from exchanges with medical experts a. Gas a no additional h230 additional hazard statement. Oct 14, 2014 hazard pictograms form part of the globally harmonized system of classification and labeling of chemicals ghs.
Hazard statements are one of the key elements for the labelling of containers under the ghs, along with. The diamondshaped pictograms indicate the nature of the hazards associated with the use of a hazardous substance or mixture. Ghs, the globally harmonized system of classification and labeling of chemicals, was developed by the united nations as a way to bring into agreement the chemical regulations and standards of different countries. Signal code hazard statements hazard class category pictogram. Accordingly, the classification of your substance or mixture determines the hazard pictograms that should be displayed on your label, for example.
The ghs chemical hazard pictograms are intended to provide the basis for or to replace national systems of hazard pictograms. The european union s 2009 classification, labelling and packaging clp regulation introduced new warning pictograms. Defines physical, health and environmental hazards of. Pdf hazard communication standard pictogram quickcard osha 3491 2016 english. The hazard symbols for chemicals were defined in annex ii of directive 67548eec. However, users are reminded that the text of the clp regulation is the only authentic legal reference and that the information in this document does not constitute legal advice. Ghs hazard pictograms solution from the conceptdraw solution park includes the set of standardized ghs hazard pictograms. Hazard statements describe the nature of the chemical hazard. European msds precautionary pictograms free pdf ebook. Sds complies with oshas hazard communication rule 29, cfr 1910. Beneath each pictogram is a listing of hazard categories represented by the corresponding image. Hazard pictograms form part of the international globally harmonized system of classification and labelling of chemicals ghs.
Reproductive toxicity specific target organ toxicity single or. Changes to chemical labels and sds euosha europa eu requirements. Two sets of pictograms are included within the ghs. Accordingly, the classification of your substance or mixture determines the hazard pictograms that should be displayed on your label, as set out in parts 2 physical hazards, 3 health hazards and 4 environmental hazards of annex i to clp clp article 19. The label shall include the relevant hazard pictogram s, intended to convey specific information on the hazard concerned. Core elements of the ghs include standardized hazard testing criteria, universal warning pictograms. Defining health, physical and environmental hazards of chemicals.
Serious health hazard vakava terveysvaara allvarlig halsofara oxidising hapettava oxiderande flammable syttyva brandfarlig corrosive syovyttava fratande health hazard terveysvaara halsofara the classification and labelling of chemicals is changing. The ghs is an acronym for the globally harmonized system of classification and labeling of chemicals. Gas 2 no pictogram warning h221 flammable gas category a chem. Recognise the new ghs hazard pictograms and hazard statements. A hazard pictogram is a pictorial presentation of a particular hazard. Minimum dimensions of labels and diamond pictograms in. Very toxic to aquatic life, with longlasting effects toxic to aquatic life, with longlasting effects examples of where we may see it. The rules they have to follow when they are classifying will change though, and a new set of hazard pictograms quite similar to the old ones are used. Each pictogram consists of a symbol on a white background framed within a red border and represents a distinct hazard s. It has still to be implemented by the european union clp regulation in 2009. Hazard pictograms alert us to the presence of a hazardous chemical.
Html pdf add to cart hazard communication standard labels quickcard osha 3492 2016 english. List of ghs hazard and precautionary statements precautionary statements general precautionary statements p101. If medical advice is needed, have product container or label at hand. Pictograms are intended to convey specific information about the hazards of a chemical. The echa website is temporarily down for maintenance. The ghs is a system for standardizing and harmonizing the classification and labeling of chemicals. Hazard communication standard pictogram the hazard communication standard hcs requires pictograms on labels to alert users of the chemical. State what information must be provided on labels and packaging. The clp regulation has introduced a new classification and labelling system for hazardous chemicals in the european union. If contact with clothes and skin, rinse with water. Pictograms will have a black symbol on a white background with a red diamond frame. Distinguish between the ghs hazard classification categories. Clp pictograms a hazard pictogram is an image on a label that includes a warning symbol and specific colours intended to provide information about the damage a particular substance or mixture can cause to our health or the environment.
Find surveys, regulations and standards, risk assessment tools, frequent hazards at work and more about workplace safety and health. Hazard pictograms ghs symbols creative safety supply. Ghs includes criteria for the classification of health, physical and environmental hazards, as well as specifying what information. Whmis pictograms, hazard classes, and hazard categories pictogram associated hazard s hazard descriptions general safe work practices the flame pictogram is used for the following classes and categories. Hazard communication standard and the globally harmonized system. Guidance on labelling and packaging in accordance with. Pictograms serve to attract attention to the hazard warnings. Platinumdivinyltetramethyldisiloxane complex in xylene. Keep away from heat, sparks, flames or hot surfaces.
The new approved pictograms will be added periodically to the annexes of this guidance. May react pictogram explosively even in the absence of air. There are 9 pictograms used in the new labeling system to convey the health, physical and environmental hazards. Hazard and precautionary information this document describes a procedure for manufacturers and suppliers to determine the pictograms, signal word, and hazard and precautionary statements required. Where a pictogram required by the department of transportation under 49 cfr appears on a shipped container, the pictogram specified in c. Code hazard statements hazard class category signal word pictogram pcodes h200 unstable explosive explosives unstable explosive danger p201, p202, p281, p372, p373, p380, p401, p501 h201 explosive. Gas 1 danger h220 extremely flammable gas category 2 flam. Ghs pictograms and hazard classes the recently updated hazard communication standard hcs requires certain pictograms be included on manufacturer and supplier labels of chemical containers to warn you of potential hazards of exposure. Hazard communication standard pictogram hcs pictograms. The minimum size of the pictograms is no more determined by the section 1. Classification and labelling clpghs internal market. Subject to article 33, hazard pictograms shall fulfil the requirements laid down in section 1. Eu osha information about occupational health and safety across eu countries.
The label of a hazardous substance or mixture includes pictograms, signal words, hazard statements, precautionary statements, and supplemental statements. Hazard communication hazcom and the globally harmonized system of classification and labeling of chemicals ghs pennsylvania technical asst. Globally harmonized system of classification and labelling. Globally harmonized system pictograms download as a pdf globally harmonized system of classification and labelling of chemicals ghs is an internationally agreedupon standard managed by the united nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. The ghs symbols have been incorporated into pictograms for use on the ghs label. The ghs has been implemented in the eu by regulation ec no 12722008 on classification, labelling and packaging of substances and mixtures the clp regulation. Convey health, physical and environmental hazard information, assigned to a ghs hazard class and category. A consolidated list with translations into other eu languages was found in directive 200159ec see the links section. Global h monized system ghs pictograms and hazards ccohso canadian centre for occupational health and safety 18006684284 ohs.
On labels, the pictograms are accompanied by signal words. The globally harmonized system of classification and labelling of chemicals ghs is a system developed by the united nations for standardizing and harmonizing the classification and labelling of chemicals globally. Consumer understanding of the safety label and pictograms on. Nphenylaminomethyltriethoxysilane safety data sheet sip6723.
Distinguish between the ghs hazard classification categories recognise the new ghs hazard pictograms and hazard statements state what information must be provided on labels and packaging. Hazard pictograms a hazard pictogram is a pictorial presentation of a particular hazard. Either one or the other is chosen, depending on the target. Listing of corresponding hazard categories for each image.
Intro to the globally harmonized system of classification and. They must be in the shape of a red outlined diamond with a black hazard symbol on a white background that is clearly visible. Under the clp regulation, pictograms with a red diamond on a white background replace the orange squares from the old system. Globally harmonized system ghs hazard communication safety data sheets quickcard osha 3493 2016 english. How to design warning infographics using transport hazard. The clp hazard pictograms are very similar to those used in the old labelling system and appear in the shape of a diamond with a distinctive red border and white. Grantee materials by topic occupational safety and. The existing legislation on classification, labelling and packaging has been agreed at european union level and, from 2015, will be directly applied on all eu member states, including the uk. Nphenylaminomethyltriethoxysilane safety data sheet print date. Oregonosha peso hazard communication ghs 10 precautionary statements supplier identification labels shall have product identifier pictograms signal word hazard statements actual labels will be different from the one shown here. This pictogram represents gases or liquids that oxidize, or lose. Hazard communication standard pictogram hcs pictograms and. Platinumdivinyltetramethyldisiloxane complex in xylene safety data sheet print date.
The clp regulation entered into force on 20 january 2009. The exploding bomb pictogram commonly indicates explosives, but it also includes substances and mixtures that are selfreactive, which can react explosively to even the most minor of physical shocks, or even a slight increase in air pressure. Ghs the new system for the classification and labeling. The newlyrequested pictogram must be approved by these regulatory bodies before its use in any submission under the terms of this guidance. Signal words a signal word indicates to the reader if a hazard is generally more severe or less severe.
Qrd guidance on the use of approved pictograms on the. A hazard pictogram is intended to provide information about the hazard that can cause damage to human health or the environment. Ghs hazard pictogram consists of a standard hazard symbol placed to the shape of a red diamond with a white background. Hazard communication standard pictogram as of june 1, 2015, the hazard communication standard hcs will require pictograms on labels to alert users of the chemical hazards to which they may be exposed. Irritation skin or eyes skin sensitization acute toxicity harmful specific target organ toxicity single exposure drowsiness or dizziness, or respiratory irritation hazardous to the ozone layer. In urgent cases, please submit your question through the contact form. The globally harmonized system of classification and labelling of chemicals ghs is an internationally agreedupon standard managed by the united nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. Clp compliant label ghs label information requirements. Consumer understanding of the safety label and pictograms.
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